ETD

Archivio digitale delle tesi discusse presso l’Università di Pisa

Tesi etd-09212015-094334

Tipo di tesi

Tesi di laurea specialistica LC5

URN

etd-09212015-094334

Titolo

Synthesis of enantiopure 2,5-dihydrofurans from D-glycal-derived vinyl epoxides and a new, simple access to a D-galactal-derived N-activated vinyl aziridine

Dipartimento

FARMACIA

Corso di studi

CHIMICA E TECNOLOGIA FARMACEUTICHE

Parole chiave

aziridine
COOMe
CSI
dihydrofuran
enolate
epoxide

Data inizio appello

07/10/2015

Consultabilità

Completa

Riassunto (Inglese)

Riassunto (Italiano)

The present experimental thesis has been focused on two aspects of the chemistry of glycal-derived vinyl epoxides and N-activated aziridines (isomerization of glycal-derived vinyl epoxides into 2,5-dihydrofurans and a new synthesis of D-galacatal-derived vinyl N-activated aziridine) and on an extended examination of synthetic value of methoxycarbonyl anion we have recently found to be generated by dimethyl malonate/LHMDS protocol.

File

Nome file	Dimensione
abstract.pdf	81.65 Kb
Chapter_1.pdf	1.02 Mb
Chapter_2.1.pdf	1.71 Mb
Chapter_2.7.pdf	1.17 Mb
Chapter_3.pdf	812.67 Kb
Chapter_4.pdf	1.72 Mb
Chapter_5.pdf	676.46 Kb
Chapter_...ental.pdf	724.47 Kb
contents.pdf	355.87 Kb
References.pdf	176.04 Kb
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