ETD

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Tesi etd-09042024-121810

Tipo di tesi

Tesi di laurea magistrale

URN

etd-09042024-121810

Titolo

Incorporating the cyano group into diiron and diruthenium complexes for potential electrocatalytic applications

Dipartimento

CHIMICA E CHIMICA INDUSTRIALE

Corso di studi

CHIMICA

Parole chiave

aminocarbyne
carbon monoxide
carbonyl group
cyanide
cyano group
cyclic voltammetry
cyclopentadienyl
dft
diiron complex
diruthenium complex
electrocatalysis
electrochemistry
her
hydrocarbyl
hydrogen
hydrogenase
iron
organometallic chemistry
ruthenium

Data inizio appello

21/10/2024

Consultabilità

Non consultabile

Data di rilascio

21/10/2027

Riassunto (Inglese)

Riassunto (Italiano)

The thesis work has focused on investigating the reactivity of a series of diiron and diruthenium bis-cyclopentadienyl complexes with the cyanide ion, affording various derivatives. Spectroscopic methods (IR, multinuclear NMR) have been employed to characterize the products, while DFT calculations have provided insights into structural and thermodynamic aspects. Preliminary electrochemical studies have been conducted to assess the potential suitability of the new complexes for electrocatalytic applications.

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