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Archivio digitale delle tesi discusse presso l’Università di Pisa

Tesi etd-06232022-151119


Tipo di tesi
Tesi di laurea magistrale
Autore
VIANELLI, GIAN PIETRO
URN
etd-06232022-151119
Titolo
Mineral filled PET compounds as recyclable alternative to thermoset composites with high thermomechanical performances
Dipartimento
CHIMICA E CHIMICA INDUSTRIALE
Corso di studi
CHIMICA INDUSTRIALE
Relatori
relatore Prof. Pucci, Andrea
correlatore Dott. Cardelli, Camillo
controrelatore Prof. Castelvetro, Valter
Parole chiave
  • PET
  • alumina
  • composites
  • mineral filler
  • chain extenders
Data inizio appello
11/07/2022
Consultabilità
Non consultabile
Data di rilascio
11/07/2025
Riassunto
In this thesis work, the preparation of composite materials based on a thermoplastic matrix and inorganic mineral fillers and their characterization in terms of thermal and mechanical behaviour have been investigated. In particular, PET-based materials filled with aluminas with different size distribution have been taken into account. More specifically, the effect of chain extenders on the processability, mechanical and thermal properties of PET-based composites have been investigated. The aim of the thesis work is to investigate the effects of the fillers and chain extenders on the thermoplastic composite material in order to obtain a novel material with high surface hardness, flexural rigidity, crystallisation rate and thermal stability, as well as the ability to maintain good mechanical properties even at temperatures higher than room temperature. Finally, the PET-based composite with the best properties has been compared with thermoset composite currently on the market. the aim of that comparison is determining whether the PET-based material could replace the filled thermoset resin on the market and up to what working temperature the properties of the thermoplastic composite were comparable to those of the thermoset material.
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