ETD

Archivio digitale delle tesi discusse presso l’Università di Pisa

Tesi etd-06092022-181212

Tipo di tesi

Tesi di laurea magistrale

URN

etd-06092022-181212

Titolo

Construction of functionalized hydrocarbyl ligands on diiron complexes

Dipartimento

CHIMICA E CHIMICA INDUSTRIALE

Corso di studi

CHIMICA

Parole chiave

aminocarbyne ligand
decarbonylation
diiron complexes
hemilability
organometallic chemistry

Data inizio appello

11/07/2022

Consultabilità

Completa

Riassunto (Inglese)

Riassunto (Italiano)

Diiron complexes derived from [Fe2Cp2(CO)4] display a rich and versatile chemistry allowing to build unusual organic fragments, exploiting the cooperative effects exerted by the two adjacent metal centres. The present work of thesis deals with the derivatization of cyano-amino-allylidene compounds. Thermal decarbonylation is a fruitful method to generate a hemilabile system. When performed in the presence of an isocyanide, this reaction provides the route to an aminocarbyne function.

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