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Archivio digitale delle tesi discusse presso l’Università di Pisa

Tesi etd-05192023-101819


Tipo di tesi
Tesi di dottorato di ricerca
Autore
FERDEGHINI, CLAUDIO
URN
etd-05192023-101819
Titolo
Sintesi, caratterizzazione e applicazione di solventi alternativi
Settore scientifico disciplinare
CHIM/06
Corso di studi
SCIENZA DEL FARMACO E DELLE SOSTANZE BIOATTIVE
Relatori
tutor Prof. Guazzelli, Lorenzo
relatore Dott. Mezzetta, Andrea
Parole chiave
  • Alternative Solvent
  • Biobased Solvents
  • Deep Eutectic Solvents
  • Dicationic Ionic Liquids
  • Green Chemistry
Data inizio appello
23/05/2023
Consultabilità
Non consultabile
Data di rilascio
23/05/2063
Riassunto
This PhD work concerns the study and application of different classes of alternatives solvents. In particular, the classes studied were the one of Dicationic Ionic Liquids, the one of Deep Eutectic Solvents and the one of Biobased solvents. The Dicationic Ionic Liquids were synthesis and studied to acquire more information about their properties. Successively, some of them were employed in a study of activation of CO2 molecules, while others were employed in the preparation of eutectic mixtures and used as media for a multicomponent reaction. Deep Eutectic Solvents and Biobased solvents were used to develop a greener protocol for the metal catalysed Suzuki-Miyaura coupling. A last project was developed involving the used of Hexafluoroisopropanol as cosolvent to enhance the rate of the Passerini multicomponent reaction.
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