Tesi etd-04222022-113929 |
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Tipo di tesi
Tesi di dottorato di ricerca
Autore
ZULLO, VALERIO
URN
etd-04222022-113929
Titolo
Exploiting chirality of isohexide scaffolds: synthesis, characterization and applications of new biobased chiral materials from isomannide and isosorbide
Settore scientifico disciplinare
CHIM/06
Corso di studi
SCIENZE CHIMICHE E DEI MATERIALI
Relatori
tutor Prof.ssa Iuliano, Anna
relatore Prof. Guazzelli, Lorenzo
relatore Prof. Guazzelli, Lorenzo
Parole chiave
- circular dichroism
- CPL
- CSA
- electrochemistry
- enantiodiscrimination
- ionic liquid
- NMR
- sugar
Data inizio appello
02/05/2022
Consultabilità
Non consultabile
Data di rilascio
02/05/2025
Riassunto
The project is focused on the synthesis of novel polyfunctional chiral compounds starting from isohexides and on their use as chiral selectors, in molecular recognition processes and as new light-emitting materials. The central idea of the project is to develop new libraries of chiral selectors and light-emitting molecules starting from polyfunctional molecules, such as isomannide and isosorbide, two sugar derived molecules obtained from the chiral pool, and using cheap reactives, simple reactions and avoiding long purfications.
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