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Archivio digitale delle tesi discusse presso l’Università di Pisa

Tesi etd-04162021-113710


Tipo di tesi
Tesi di laurea magistrale
Autore
PASSUTI, SARA
URN
etd-04162021-113710
Titolo
Electron crystallography of Metal-Organic Frameworks
Dipartimento
INGEGNERIA CIVILE E INDUSTRIALE
Corso di studi
MATERIALS AND NANOTECHNOLOGY
Relatori
relatore Prof. Lazzeri, Andrea
relatore Prof. Gemmi, Mauro
correlatore Dott.ssa Lanza, Arianna
Parole chiave
  • crystal structure
  • electron diffraction
  • metal-organic framework
Data inizio appello
07/05/2021
Consultabilità
Non consultabile
Data di rilascio
07/05/2091
Riassunto
This thesis work is focused on synthesis and crystal structure characterization of Metal-Organic Frameworks (MOFs). We exploited solvothermal synthesis in order to replicate the reference Zn-btca and Mn-btca MOF structures. Successively, we tried metal ion substitution of the synthesised samples with the aim of obtaining bimetallic MOFs. We also tried to synthesise new monometallic and bimetallic MOF structures with solvothermal and mechanochemical synthetic approaches. We used Powder X-Ray Diffraction (PXRD), Electron Diffraction (ED) and Energy Dispersive X-ray spectroscopy (EDX) to characterize the obtained samples from a structural and compositional point of view.
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