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Archivio digitale delle tesi discusse presso l’Università di Pisa

Tesi etd-04062021-193108


Tipo di tesi
Tesi di dottorato di ricerca
Autore
CESARI, ANDREA
URN
etd-04062021-193108
Titolo
The Role of NMR Spectroscopy in the Rationalization of Materials Properties
Settore scientifico disciplinare
CHIM/06
Corso di studi
SCIENZE CHIMICHE E DEI MATERIALI
Relatori
tutor Prof.ssa Uccello Barretta, Gloria
Parole chiave
  • cyclodextrins
  • hybrid organic-inorganic perovskites
  • maltodextrins
  • modified chitosans
  • nanosponges
  • NMR
  • transition metal dichalcogenide (WS2)
Data inizio appello
14/04/2021
Consultabilità
Non consultabile
Data di rilascio
14/04/2027
Riassunto
The present PhD thesis focused on the use of Nuclear Magnetic Resonance (NMR) spectroscopy for the in-depth comprehensive study of the stereochemical, dynamic and thermodynamic features of supramolecular aggregates involving from low-to-high molecular weight systems. Three main kinds of materials with high technological impact were investigated: 1) derivatized ammonium-chitosans to be employed, also as nanoparticles, for drug delivery systems; 2) cyclodextrins and maltodextrins as solubility promoters and controlled release platforms, respectively; 3) inorganic or hybrid organic/inorganic optoelectronic components, in which the comprehension of the role of organic species used in synthetic procedures is fundamental for the rational design of optimized final materials.
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