ETD

Archivio digitale delle tesi discusse presso l’Università di Pisa

Tesi etd-03072014-095644

Tipo di tesi

Tesi di laurea magistrale

URN

etd-03072014-095644

Titolo

Synthesis and characterization of Molybdenum(VI) complexes with α-amino acids

Dipartimento

CHIMICA E CHIMICA INDUSTRIALE

Corso di studi

CHIMICA

Parole chiave

amino acid
coordination polymer
cyclohexene oxidation
molybdenum

Data inizio appello

10/04/2014

Consultabilità

Completa

Riassunto (Inglese)

Riassunto (Italiano)

Dioxomolybdenum(VI) complexes containing α-amino acids as ligands were prepared and characterized by means of IR and solid state NMR spectroscopy. The formation of these compounds has been extensively studied. The proposed polymeric structure, [{Mo2O4(OH)2(aaH)}(u-O)]n, is supported by DFT calculations. The catalytic activity in the oxidation of cyclohexene by H2O2 in acetonitrile was tested.

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Biancala...acids.pdf	1.67 Mb
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