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Tesi etd-03072014-095644

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Tipo di tesi
Tesi di laurea magistrale
Autore
BIANCALANA, LORENZO
URN
etd-03072014-095644
Titolo
Synthesis and characterization of Molybdenum(VI) complexes with α-amino acids
Dipartimento
CHIMICA E CHIMICA INDUSTRIALE
Corso di studi
CHIMICA
Relatori
relatore Prof. Pampaloni, Guido
correlatore Prof. Labella, Luca
Parole chiave
  • amino acid
  • coordination polymer
  • cyclohexene oxidation
  • molybdenum
Data inizio appello
10/04/2014
Consultabilità
Completa
Riassunto
Dioxomolybdenum(VI) complexes containing α-amino acids as ligands were prepared and characterized by means of IR and solid state NMR spectroscopy. The formation of these compounds has been extensively studied. The proposed polymeric structure, [{Mo2O4(OH)2(aaH)}(u-O)]n, is supported by DFT calculations. The catalytic activity in the oxidation of cyclohexene by H2O2 in acetonitrile was tested.
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Biancala...acids.pdf 1.67 Mb
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