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Tesi etd-02242020-093511


Tipo di tesi
Tesi di dottorato di ricerca
Autore
BRESCIANI, GIULIO
URN
etd-02242020-093511
Titolo
Carbon Dioxide: an Attractive Building Block for Inorganic and Organic Compounds
Settore scientifico disciplinare
CHIM/03
Corso di studi
SCIENZE CHIMICHE E DEI MATERIALI
Relatori
tutor Prof. Pampaloni, Guido
Parole chiave
  • carbon dioxide
  • catalysts
  • inorganic complexes
  • metal carbamates
Data inizio appello
06/03/2020
Consultabilità
Completa
Riassunto
The employment of carbon dioxide as C1-unit to build inorganic and organic compounds was investigated.
New metal carbamates were synthesized and characterized using different strategies.
These complexes were tested as catalytic precursors in some different carbon dioxide activation reactions using reaction conditions as mild as possible.
Attention was paid in the study of catalysts action mechanisms employing spectroscopic measurements and DFT calculations.
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