Tipo di tesi
Tesi di dottorato di ricerca
Titolo
Synthesis, structural and dynamic investigation of chiral metal complexes
Settore scientifico disciplinare
CHIM/06 - CHIMICA ORGANICA
Corso di studi
SCIENZE DI BASE
Riassunto (Italiano)
This thesis work epitomizes our experience in the solution structure investigation of chiral lanthanide complexes through a dual paramagnetic NMR/chiroptical spectroscopies method. During my work I have studied the LnM(hfbc)4 system (M alkali metal, hfbc = heptafluorobutyrilcamphorate) and pointed out the connection between the solution structure and its glum dissymetry factor. I have also pointed out a novel effect of enhancement of the VCD signal in presence of a paramagnetic Ln ion for chiral complexes or chiral adducts with natural occuring chiral organic molecules.
