Tesi etd-01092013-194340 |
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Tipo di tesi
Tesi di dottorato di ricerca
Autore
DI PIETRO, SEBASTIANO
URN
etd-01092013-194340
Titolo
Synthesis, structural and dynamic investigation of chiral metal complexes
Settore scientifico disciplinare
CHIM/06
Corso di studi
SCIENZE DI BASE
Relatori
tutor Prof. Di Bari, Lorenzo
controrelatore Dott. Mazzanti, Marinella
commissario Prof. Marchetti, Fabio
commissario Prof. Goti, Andrea
commissario Prof. Casu, Mariano
commissario Prof. Harris, Robin K.
controrelatore Dott. Mazzanti, Marinella
commissario Prof. Marchetti, Fabio
commissario Prof. Goti, Andrea
commissario Prof. Casu, Mariano
commissario Prof. Harris, Robin K.
Parole chiave
- CD
- Chiral
- Circular Dichroism
- Complexes
- CPL
- fluorescence
- Lanthanide
- NMR
- Paramagnetic
- solution structure
- VCD
Data inizio appello
28/01/2013
Consultabilità
Completa
Riassunto
This thesis work epitomizes our experience in the solution structure investigation of chiral lanthanide complexes through a dual paramagnetic NMR/chiroptical spectroscopies method. During my work I have studied the LnM(hfbc)4 system (M alkali metal, hfbc = heptafluorobutyrilcamphorate) and pointed out the connection between the solution structure and its glum dissymetry factor. I have also pointed out a novel effect of enhancement of the VCD signal in presence of a paramagnetic Ln ion for chiral complexes or chiral adducts with natural occuring chiral organic molecules.
File
| Nome file | Dimensione |
|---|---|
| Di_Pietr...hesis.pdf | 10.81 Mb |
| Errataco...hesis.pdf | 155.54 Kb |
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