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Tesi etd-09232019-115556


Thesis type
Tesi di laurea magistrale
Author
ANTICO, EMANUELE
URN
etd-09232019-115556
Title
Synthetic pathways to heterocyclic compounds via CO2 activation: is the metal catalyst really needed?
Struttura
CHIMICA E CHIMICA INDUSTRIALE
Corso di studi
CHIMICA
Commissione
relatore Prof. Marchetti, Fabio
Parole chiave
  • heterocycles
  • carbon dioxide
  • activation
  • lactones
  • oxazolidinones
Data inizio appello
22/10/2019;
Consultabilità
secretata d'ufficio
Data di rilascio
22/10/2022
Riassunto analitico
This work has the aim to use carbon dioxide as a chemical resource in organic synthesis, and this has been done through the absence of a catalyst, and a stoichiometric organometallic reagent. In literature instead normally the carbon dioxide activation needs a metal catalyst. The target molecules of this thesis are heterocycles: 2-oxazolidinones and butyrolactones. Both this functionalities are common structural patterns in drugs and in natural compounds, so it would be interesting to perform synthesis of this functionalities through the carbon dioxide as a mono-carbon source.
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