Thesis etd-09232019-115556 |
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Thesis type
Tesi di laurea magistrale
URN
etd-09232019-115556
Thesis title
Synthetic pathways to heterocyclic compounds via CO2 activation: is the metal catalyst really needed?
Department
CHIMICA E CHIMICA INDUSTRIALE
Course of study
CHIMICA
Supervisors
.
relatore Prof. Marchetti, Fabio
Keywords
- activation
- carbon dioxide
- heterocycles
- lactones
- oxazolidinones
Graduation session start date
22/10/2019
Availability
Withheld
Release date
22/10/2089
Abstract (Inglese)
Abstract (Italiano)
This work has the aim to use carbon dioxide as a chemical resource in organic synthesis, and this has been done through the absence of a catalyst, and a stoichiometric organometallic reagent. In literature instead normally the carbon dioxide activation needs a metal catalyst. The target molecules of this thesis are heterocycles: 2-oxazolidinones and butyrolactones. Both this functionalities are common structural patterns in drugs and in natural compounds, so it would be interesting to perform synthesis of this functionalities through the carbon dioxide as a mono-carbon source.
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