Thesis etd-09212015-094334 |
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Thesis type
Tesi di laurea specialistica LC5
URN
etd-09212015-094334
Thesis title
Synthesis of enantiopure 2,5-dihydrofurans from D-glycal-derived vinyl epoxides and a new, simple access to a D-galactal-derived N-activated vinyl aziridine
Department
FARMACIA
Course of study
CHIMICA E TECNOLOGIA FARMACEUTICHE
Supervisors
.
relatore Prof. Crotti, Paolo
relatore Dott.ssa Di Bussolo, Valeria
relatore Dott.ssa Di Bussolo, Valeria
Keywords
- aziridine
- COOMe
- CSI
- dihydrofuran
- enolate
- epoxide
Graduation session start date
07/10/2015
Availability
Full
Abstract (Inglese)
Abstract (Italiano)
The present experimental thesis has been focused on two aspects of the chemistry of glycal-derived vinyl epoxides and N-activated aziridines (isomerization of glycal-derived vinyl epoxides into 2,5-dihydrofurans and a new synthesis of D-galacatal-derived vinyl N-activated aziridine) and on an extended examination of synthetic value of methoxycarbonyl anion we have recently found to be generated by dimethyl malonate/LHMDS protocol.
File
| Nome file | Dimensione |
|---|---|
| abstract.pdf | 81.65 Kb |
| Chapter_1.pdf | 1.02 Mb |
| Chapter_2.1.pdf | 1.71 Mb |
| Chapter_2.7.pdf | 1.17 Mb |
| Chapter_3.pdf | 812.67 Kb |
| Chapter_4.pdf | 1.72 Mb |
| Chapter_5.pdf | 676.46 Kb |
| Chapter_...ental.pdf | 724.47 Kb |
| contents.pdf | 355.87 Kb |
| References.pdf | 176.04 Kb |
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