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Tesi etd-09212015-094334


Thesis type
Tesi di laurea specialistica LC5
Author
PRINCIOTTO, SALVATORE
URN
etd-09212015-094334
Title
Synthesis of enantiopure 2,5-dihydrofurans from D-glycal-derived vinyl epoxides and a new, simple access to a D-galactal-derived N-activated vinyl aziridine
Struttura
FARMACIA
Corso di studi
CHIMICA E TECNOLOGIA FARMACEUTICHE
Commissione
relatore Prof. Crotti, Paolo
relatore Dott.ssa Di Bussolo, Valeria
Parole chiave
  • COOMe
  • CSI
  • aziridine
  • dihydrofuran
  • enolate
  • epoxide
Data inizio appello
07/10/2015;
Consultabilità
parziale
Data di rilascio
07/10/2018
Riassunto analitico
The present experimental thesis has been focused on two aspects of the chemistry of glycal-derived vinyl epoxides and N-activated aziridines (isomerization of glycal-derived vinyl epoxides into 2,5-dihydrofurans and a new synthesis of D-galacatal-derived vinyl N-activated aziridine) and on an extended examination of synthetic value of methoxycarbonyl anion we have recently found to be generated by dimethyl malonate/LHMDS protocol.
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