ETD

Archivio digitale delle tesi discusse presso l'Università di Pisa

Tesi etd-09142020-163152


Tipo di tesi
Tesi di laurea magistrale
Autore
CAMPORA, LORENZO DONATO
URN
etd-09142020-163152
Titolo
Biomacromolecules from renewable biomass for sustainable and active coatings on cellulosic and plastic substrates
Dipartimento
INGEGNERIA CIVILE E INDUSTRIALE
Corso di studi
MATERIALS AND NANOTECHNOLOGY
Relatori
relatore Prof.ssa Cinelli, Patrizia
correlatore Prof.ssa Coltelli, Maria Beatrice
supervisore Dott. Fürtauer, Siegfried
Parole chiave
  • nanocellulose
  • coating
  • chitin
  • cellulose
  • biopolymers
  • bioplastics
  • biodgradable
  • nanochitin
  • polymers
  • sustainable
Data inizio appello
02/10/2020
Consultabilità
Completa
Riassunto
The biopolymer market has received a major attention in the last years, due to increasing attention to the environment and pollution-related issues. Research is pushing towards the development of cheap and competitive materials to gradually replace synthetic plastics.
Tons of plastics, utilized in the food packaging sector, are being wasted every year. The use of biodegradable polymer can help to solve these sustainability-related issues, as conducted in this thesis work.
A strategy to enhance the barrier properties of bioplastics, while maintaining an ecological approach, is based on the development of biobased and fully degradable coatings.
Chitin and Cellulose are two of the most abundant biopolymers on earth, and were used to produce sustainable and fully degradable material.
Nanochitin has shown to have antibacterial properties and Nanocellulose to increase the barrier properties (i.e. oxygen permeability) of the coated materials.
The production of hot-melt and water-born coatings on plastic substrates, blending nanochitin with lactic acid oligomers and fully biodegradable co-polyesters has been achieved.
Also, a protocol to modify nanocellulose utilizing silanols and food contact approved solvents (water, acetone) has been tested and optimized with promising results.
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