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Tesi etd-03072014-095644


Thesis type
Tesi di laurea magistrale
Author
BIANCALANA, LORENZO
URN
etd-03072014-095644
Title
Synthesis and characterization of Molybdenum(VI) complexes with α-amino acids
Struttura
CHIMICA E CHIMICA INDUSTRIALE
Corso di studi
CHIMICA
Commissione
relatore Prof. Pampaloni, Guido
correlatore Prof. Labella, Luca
Parole chiave
  • cyclohexene oxidation
  • coordination polymer
  • amino acid
  • molybdenum
Data inizio appello
10/04/2014;
Consultabilità
completa
Riassunto analitico
Dioxomolybdenum(VI) complexes containing α-amino acids as ligands were prepared and characterized by means of IR and solid state NMR spectroscopy. The formation of these compounds has been extensively studied. The proposed polymeric structure, [{Mo2O4(OH)2(aaH)}(u-O)]n, is supported by DFT calculations. The catalytic activity in the oxidation of cyclohexene by H2O2 in acetonitrile was tested.
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