Thesis etd-02242020-093511 |
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Thesis type
Tesi di dottorato di ricerca
Author
BRESCIANI, GIULIO
URN
etd-02242020-093511
Thesis title
Carbon Dioxide: an Attractive Building Block for Inorganic and Organic Compounds
Academic discipline
CHIM/03
Course of study
SCIENZE CHIMICHE E DEI MATERIALI
Supervisors
tutor Prof. Pampaloni, Guido
Keywords
- carbon dioxide
- catalysts
- inorganic complexes
- metal carbamates
Graduation session start date
06/03/2020
Availability
Full
Summary
The employment of carbon dioxide as C1-unit to build inorganic and organic compounds was investigated.
New metal carbamates were synthesized and characterized using different strategies.
These complexes were tested as catalytic precursors in some different carbon dioxide activation reactions using reaction conditions as mild as possible.
Attention was paid in the study of catalysts action mechanisms employing spectroscopic measurements and DFT calculations.
New metal carbamates were synthesized and characterized using different strategies.
These complexes were tested as catalytic precursors in some different carbon dioxide activation reactions using reaction conditions as mild as possible.
Attention was paid in the study of catalysts action mechanisms employing spectroscopic measurements and DFT calculations.
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