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ETD

Digital archive of theses discussed at the University of Pisa

 

Thesis etd-01112021-091451


Thesis type
Tesi di laurea magistrale
Author
BARTOLI, OMAR
URN
etd-01112021-091451
Thesis title
Thermochemical Energy Storage using Ca(OH)2/CaO reversible reaction
Department
INGEGNERIA DELL'ENERGIA, DEI SISTEMI, DEL TERRITORIO E DELLE COSTRUZIONI
Course of study
INGEGNERIA ENERGETICA
Supervisors
relatore Prof. Desideri, Umberto
Keywords
  • Ca(OH)2
  • CaO
  • dehydration
  • fluidized bed reactor
  • hydration
  • termochemical energy storage
Graduation session start date
11/02/2021
Availability
Full
Summary
This work analyses a thermochemical energy storage process using Ca(OH)2/CaO chemical loop. A fluidized bed reactor is proposed to carry out the dehydration-hydration process (respectively charging and discharging stages) alternating reaction. The processes use superheated steam as the fluidizing agent. The model proposed is analyzed by sensitivity analysies, focused on the effects on the reactor performance when temperature and pressure of the inlet flows are changed. Also, the geometry of the reactor and the solid particle size distribution are investigated. Results obtained, in terms of solids conversion and heat duty required/provided from the reactor during the charging and discharging step respectively, leads to a possible integration whit a Rankine-Hirn cycle for electric production. The model of the study has been implemented by software Aspen Plus.
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