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Tesi etd-10072014-131847


Thesis type
Elaborati finali per laurea triennale
Author
BIANCALANA, LORENZO
URN
etd-10072014-131847
Title
Reattività di TiF4 con potenziali leganti bidentati all'ossigeno
Struttura
CHIMICA E CHIMICA INDUSTRIALE
Corso di studi
CHIMICA
Commissione
relatore Prof. Pampaloni, Guido
relatore Dott. Marchetti, Fabio
tutor Prof.ssa Ribechini, Erika
Parole chiave
  • Titanium Tetrafluoride
  • C-C bond activation
  • O-Donor ligands
  • acetals/ketals
Data inizio appello
22/09/2011;
Consultabilità
completa
Riassunto analitico
The aim of this work was the study of TiF4- and TiF4(NCMe)2- promoted activation reactions of a series of organic molecules (acetals, ketals, alcohols, epoxides, diazo compounds). Reactions have been carried out under a nitrogen atmosphere; organic products have been characterized by means of IR analysis, NMR, and GC-MS. Fragmentation and/or rearrangement of the organic moiety has been observed; it generally occurs unselectively via C-O bond fission and formation of new C-O, C-H and C-C bonds.
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