Thesis etd-10072014-131847 |
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Thesis type
Elaborati finali per laurea triennale
Author
BIANCALANA, LORENZO
URN
etd-10072014-131847
Thesis title
Reattività di TiF4 con potenziali leganti bidentati all'ossigeno
Department
CHIMICA E CHIMICA INDUSTRIALE
Course of study
CHIMICA
Supervisors
relatore Prof. Pampaloni, Guido
relatore Dott. Marchetti, Fabio
tutor Prof.ssa Ribechini, Erika
relatore Dott. Marchetti, Fabio
tutor Prof.ssa Ribechini, Erika
Keywords
- Titanium Tetrafluoride
- C-C bond activation
- O-Donor ligands
- acetals/ketals
Graduation session start date
22/09/2011
Availability
Full
Summary
The aim of this work was the study of TiF4- and TiF4(NCMe)2- promoted activation reactions of a series of organic molecules (acetals, ketals, alcohols, epoxides, diazo compounds). Reactions have been carried out under a nitrogen atmosphere; organic products have been characterized by means of IR analysis, NMR, and GC-MS. Fragmentation and/or rearrangement of the organic moiety has been observed; it generally occurs unselectively via C-O bond fission and formation of new C-O, C-H and C-C bonds.
File
| Nome file | Dimensione |
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| Reattivi...igeno.pdf | 544.32 Kb |
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