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ETD

Digital archive of theses discussed at the University of Pisa

 

Thesis etd-10042021-114229


Thesis type
Tesi di laurea magistrale
Author
CARGIOLI, ALESSIO
email address
a.cargioli@studenti.unipi.it, alessiocargioli@libero.it
URN
etd-10042021-114229
Thesis title
Optical Microcavities Based on Organic Photoswitchable Systems in the Strong Coupling Regime
Department
FISICA
Course of study
FISICA
Supervisors
relatore Prof. Tredicucci, Alessandro
relatore Dott.ssa Persano, Luana
correlatore Dott. Camposeo, Andrea
Keywords
  • cavity polaritons
  • energy transport
  • photoswitchable molecules
  • strong coupling
Graduation session start date
25/10/2021
Availability
Full
Summary
Polariton mediated long range energy transport has been measured in different donor-acceptor systems including organic molecules such as J-aggregates and BODIPY dyes. Nevertheless, there is still a necessity of understanding at a deeper level how the transport actually happens, how the dark states and the environment coupling can influence it and if it is possible to control it by engineering the molecules undergoing strong coupling. In this thesis, the donor molecule is chosen to be photoisomerizable under UV and green light exposure to the purpose of controlling, through an external optical gate, the polariton formation and the energy transport. For this reason, Silver and DBR microcavities embedding spatially separated donor and acceptor molecules are designed, fabricated and optically characterized through angle resolved reflectivity, transmittivity and emission measurements.
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