Thesis etd-06092022-181212 |
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Thesis type
Tesi di laurea magistrale
URN
etd-06092022-181212
Thesis title
Construction of functionalized hydrocarbyl ligands on diiron complexes
Department
CHIMICA E CHIMICA INDUSTRIALE
Course of study
CHIMICA
Supervisors
.
relatore Prof. Marchetti, Fabio
Keywords
- aminocarbyne ligand
- decarbonylation
- diiron complexes
- hemilability
- organometallic chemistry
Graduation session start date
11/07/2022
Availability
Full
Abstract (Inglese)
Abstract (Italiano)
Diiron complexes derived from [Fe2Cp2(CO)4] display a rich and versatile chemistry allowing to build unusual organic fragments, exploiting the cooperative effects exerted by the two adjacent metal centres. The present work of thesis deals with the derivatization of cyano-amino-allylidene compounds. Thermal decarbonylation is a fruitful method to generate a hemilabile system. When performed in the presence of an isocyanide, this reaction provides the route to an aminocarbyne function.
File
| Nome file | Dimensione |
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| TesiChia...pelli.pdf | 2.45 Mb |
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