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Digital archive of theses discussed at the University of Pisa

 

Thesis etd-05262017-145958


Thesis type
Tesi di laurea magistrale
URN
etd-05262017-145958
Thesis title
Novel polymer composites by black phosphorus dispersion
Department
CHIMICA E CHIMICA INDUSTRIALE
Course of study
CHIMICA INDUSTRIALE
Supervisors
.
relatore Dott.ssa Passaglia, Elisa
relatore Dott.ssa Cicogna, Francesca
controrelatore Prof. Geppi, Marco
Keywords
  • black phosphorus
  • phosphorene
  • polymer composites
Graduation session start date
15/06/2017
Availability
Full
Abstract (Inglese)
Abstract (Italiano)
Black phosphorus flakes (bP)and phosphorene dispersion were used as fillers for polymeric matrices. Polystyrene (PS) polymethyl(methacrylate) (PMMA), poly(lacti acid) (PLA), poly vinyl pyrrolidone (PVP) were used to prepare nanocomposites with different methodologies: polymer solution intercalation of phosphorene suspension, liquid phase exfoliation of bP by polymeric solutions, and liquid phase exfoliation of bP by monomers followed by in-situ polymerization. Finally, the morphology, the structure and the thermal properties of these polymer nanocomposites were analysed with the aim to evaluate the possible interaction of bP crystalline phase and the macromolecular chains.
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