Thesis etd-04222022-113929 |
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Thesis type
Tesi di dottorato di ricerca
URN
etd-04222022-113929
Thesis title
Exploiting chirality of isohexide scaffolds: synthesis, characterization and applications of new biobased chiral materials from isomannide and isosorbide
Academic discipline
CHIM/06 - CHIMICA ORGANICA
Course of study
SCIENZE CHIMICHE E DEI MATERIALI
Supervisors
.
tutor Prof.ssa Iuliano, Anna
relatore Prof. Guazzelli, Lorenzo
relatore Prof. Guazzelli, Lorenzo
Keywords
- circular dichroism
- CPL
- CSA
- electrochemistry
- enantiodiscrimination
- ionic liquid
- NMR
- sugar
Graduation session start date
02/05/2022
Availability
Withheld
Release date
02/05/2025
Abstract (Inglese)
Abstract (Italiano)
The project is focused on the synthesis of novel polyfunctional chiral compounds starting from isohexides and on their use as chiral selectors, in molecular recognition processes and as new light-emitting materials. The central idea of the project is to develop new libraries of chiral selectors and light-emitting molecules starting from polyfunctional molecules, such as isomannide and isosorbide, two sugar derived molecules obtained from the chiral pool, and using cheap reactives, simple reactions and avoiding long purfications.
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