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Archivio digitale delle tesi discusse presso l’Università di Pisa

Tesi etd-08282021-160723


Tipo di tesi
Tesi di laurea magistrale
Autore
CAROTI, GIULIA
URN
etd-08282021-160723
Titolo
Unravelling the chemistry of cadmium red oil paints by mass spectrometry and thermoanalytical techniques using methyl esters as model binders.
Dipartimento
CHIMICA E CHIMICA INDUSTRIALE
Corso di studi
CHIMICA
Relatori
relatore Prof.ssa Bonaduce, Ilaria
Parole chiave
  • Cadmium red
  • Linseed oil
  • Lipid binders
  • Mass spectrometry
  • Methyl esters
  • Methyl linoleate
  • Methyl linolenate
  • Safflower oil
  • Thermoanalytical techniques
Data inizio appello
13/09/2021
Consultabilità
Non consultabile
Data di rilascio
13/09/2027
Riassunto
The target of the thesis is to unravel how cadmium red influences the curing of an oil paint. Oil paint is a form of a slow-drying paint that consists of particles of pigment suspended in a vegetable drying oil that forms a solid elastic film upon exposure to air. Linseed oil is one of the most common oils used since the antiquity and generates stable and resistant films, but the main drawback of this oil is that this films tent to yellow with ageing. Because of this, with the advent of the Industrial Revolution, the artists started to use new types of oils, such as safflower oil, which is a semi-drying oil. At the molecular level, methyl esters are simpler than triglycerides and for this reason the mass spectral features of compounds produced upon its curing are significantly simplified. To achieved the target, mass spectrometry and thermoanalytical techniques have been used. Cadmium red is a mineral inorganic pigment and is a solid solution of sulfur and selenium.
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